\u5bfc\u8a00\uff1a \u968f\u77402010\u5e74\u8bfa\u8d1d\u5c14\u7269\u7406\u5b66\u5956\u9881\u7ed9\u4e86\u77f3\u58a8\u70ef\u7684\u53d1\u660e\u8005 \u2014\u2014\u4e24\u4f4d\u82f1\u56fd\u7269\u7406\u5b66\u5bb6\u5b89\u5fb7\u70c8\u548c\u5eb7\u65af\u5766\u4e01\uff0c\u4e00\u65f6\u95f4\u79d1\u7814\u5708\u6380\u8d77\u4e86\u4e00\u80a1\u77f3\u58a8\u70ef\u7684\u7814\u7a76\u70ed\u6f6e\u3002\u77f3\u58a8\u70ef\u4e5f\u6210\u4e3a\u4e86\u8d8a\u6765\u8d8a\u591a\u79d1\u5b66\u5bb6\u9009\u62e9\u7684\u6750\u6599\u3002<\/p>\n
\u540c\u6837\u662f2010\u5e74\uff0c\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u7684\u7814\u7a76\u4eba\u5458\u7ecf\u8fc7\u6f5c\u5fc3\u7814\u7a76\u53d1\u660e\u4e86\u78b3\u5bb6\u65cf\u7684\u65b0\u6210\u5458\uff1a\u77f3\u58a8\u7094\uff0c\u8fd9\u662f\u4e00\u4e2a\u4ee4\u4eba\u632f\u594b\u7684\u91cd\u5927\u7a81\u7834\u3002<\/p>\n
\u4eba\u4eec\u4e0d\u7981\u4f1a\u95ee\u77f3\u58a8\u7094\u6700\u8fd1\u53d1\u5c55\u5f97\u5982\u4f55\uff0c\u77f3\u58a8\u70ef\u548c\u77f3\u58a8\u7094\u7a76\u7adf\u5b70\u4f18\u5b70\u52a3\uff0c\u201c\u6d0b\u8d27\u201d\u548c\u201c\u56fd\u8d27\u201d\u8c01\u66f4\u80fd\u4e3b\u5bfc\u672a\u6765\u7684\u8bdd\u8bed\u6743?\u4e14\u542c\u5c0f\u7f16\u7ec6\u7ec6\u9053\u6765\u3002<\/p>\n<\/p>\n
\u78b3\u5bb6\u65cf\u7684\u65b0\u6210\u5458<\/p>\n
\u5408\u6210\u3001\u5206\u79bb\u65b0\u7684\u4e0d\u540c\u7ef4\u6570\u78b3\u540c\u7d20\u5f02\u5f62\u4f53\u662f\u8fc7\u53bb\u4e8c\u4e09\u5341\u5e74\u7814\u7a76\u7684\u7126\u70b9\uff0c\u79d1\u5b66\u5bb6\u4eec\u5148\u540e\u53d1\u73b0\u4e86\u4e09\u7ef4\u5bcc\u52d2\u70ef\u3001\u4e00\u7ef4\u78b3\u7eb3\u7c73\u7ba1\u548c\u4e8c\u7ef4\u77f3\u58a8\u70ef\u7b49\u65b0\u7684\u78b3\u540c\u7d20\u5f02\u5f62\u4f53\uff0c\u8fd9\u4e9b\u6750\u6599\u5747\u6210\u4e3a\u4e86\u56fd\u9645\u5b66\u672f\u7814\u7a76\u7684\u524d\u6cbf\u548c\u70ed\u70b9\u3002\u78b3\u6750\u6599\u53ef\u5e7f\u6cdb\u5e94\u7528\u4e8e\u9502\u79bb\u5b50\u7535\u6c60\u3001\u8d85\u7ea7\u7535\u5bb9\u5668\u3001\u4f20\u611f\u5668\u3001\u592a\u9633\u80fd\u7535\u6c60\u3001\u50ac\u5316\u8f7d\u4f53\u4ee5\u53ca\u7eb3\u5fae\u7535\u5b50\u5668\u4ef6\u7b49\u9886\u57df\u7814\u7a76\u3002\u78b3\u5177\u6709sp3\u3001sp2\u548csp\u4e09\u79cd\u6742\u5316\u6001\uff0c\u901a\u8fc7\u4e0d\u540c\u6742\u5316\u6001\u53ef\u4ee5\u5f62\u6210\u591a\u79cd\u78b3\u7684\u540c\u7d20\u5f02\u5f62\u4f53\uff0c\u5982\uff1a\u901a\u8fc7sp3\u6742\u5316\u53ef\u4ee5\u5f62\u6210\u91d1\u521a\u77f3\uff0c\u901a\u8fc7sp3\u4e0esp2\u6742\u5316\u5219\u53ef\u4ee5\u5f62\u6210\u78b3\u7eb3\u7c73\u7ba1\u3001\u5bcc\u52d2\u70ef\u548c\u77f3\u58a8\u70ef\u7b49\u30021996\u5e74\u5316\u5b66\u8bfa\u8d1d\u5c14\u5956\u88ab\u6388\u4e88\u4e863\u4f4d\u5bcc\u52d2\u70ef\u7684\u53d1\u73b0\u8005\uff0c2010\u5e74\u82f1\u56fd\u66fc\u5f7b\u65af\u7279\u5927\u5b66\u7684\u5b89\u5fb7\u70c8\u00b7\u6d77\u59c6\u548c\u5eb7\u65af\u5766\u4e01\u00b7\u8bfa\u6c83\u8096\u6d1b\u592b\u7531\u4e8e\u5728\u4e8c\u7ef4\u6750\u6599\u77f3\u58a8\u70ef\u65b9\u9762\u5f00\u521b\u6027\u7684\u7814\u7a76\u88ab\u6388\u4e88\u4e86\u8bfa\u8d1d\u5c14\u7269\u7406\u5956\uff0c\u4f7f\u5f97\u78b3\u6750\u6599\u7684\u7814\u7a76\u8fdb\u5165\u4e86\u4e00\u4e2a\u65b0\u7684\u9636\u6bb5\uff0c\u540c\u65f6\u4e5f\u6fc0\u8d77\u4e86\u79d1\u5b66\u5bb6\u4eec\u5bf9\u65b0\u578b\u78b3\u7684\u540c\u7d20\u5f02\u5f62\u4f53\u7684\u7814\u7a76\u7684\u70ed\u5ff1\u548c\u5174\u8da3\u3002<\/p>\n
\u7531\u4e8esp\u6742\u5316\u6001\u5f62\u6210\u7684\u78b3\u78b3\u4e09\u952e\u5177\u6709\u7ebf\u6027\u7ed3\u6784\u3001\u65e0\u987a\u53cd\u5f02\u6784\u4f53\u548c\u9ad8\u5171\u8f6d\u7b49\u4f18\u70b9\uff0c\u4eba\u4eec\u4e00\u76f4\u6e34\u671b\u80fd\u591f\u83b7\u5f97\u5177\u6709sp\u6742\u5316\u6001\u7684\u78b3\u7684\u65b0\u540c\u7d20\u5f02\u5f62\u4f53\uff0c\u5e76\u8ba4\u4e3a\u8be5\u7c7b\u78b3\u6750\u6599\u5177\u5907\u4f18\u5f02\u7684\u7535\u5b66\u3001\u5149\u5b66\u548c\u5149\u7535\u6027\u80fd\uff0c\u5c06\u6210\u4e3a\u4e0b\u4e00\u4ee3\u65b0\u7684\u7535\u5b50\u548c\u5149\u7535\u5668\u4ef6\u7684\u5173\u952e\u6750\u6599\u3002\u5c31\u5728\u8fd9\u65f6\uff0c\u6211\u56fd\u79d1\u5b66\u5bb6\u7ecf\u8fc7\u52aa\u529b\u5728\u4e16\u754c\u8303\u56f4\u5185\u9996\u6b21\u89c1\u8bc1\u4e86\u78b3\u5bb6\u65cf\u65b0\u6210\u5458\u7684\u8bde\u751f\u2014\u2014\u77f3\u58a8\u7094\u3002<\/p>\n<\/p>\n
\u78b3\u5bb6\u65cf\u5168\u5bb6\u798f<\/p>\n
\u7a3b\u8349\u8fd8\u662f\u9ec4\u91d1?<\/p>\n
2010\u5e74\uff0c\u5c31\u5728\u4e3a\u77f3\u58a8\u70ef\u83b7\u5f97\u8bfa\u8d1d\u5c14\u7269\u7406\u5b66\u5956\u6b22\u547c\u96c0\u8dc3\u4e4b\u65f6\uff0c\u6211\u56fd\u79d1\u5b66\u5bb6\u5728Chem. Commun.\u6742\u5fd7\u4e0a\u9996\u6b21\u62a5\u9053\u4e86\u78b3\u5bb6\u65cf\u65b0\u6210\u5458\u77f3\u58a8\u7094\u7684\u8bde\u751f\u3002<\/p>\n
\u4e00\u65f6\u95f4\uff0c\u4e16\u754c\u8fd8\u6ca1\u6709\u7f13\u8fc7\u795e\u6765\u3002\u77f3\u58a8\u70ef\u662f\u4ec0\u4e48\u8fd8\u4f3c\u61c2\u975e\u61c2\uff0c\u77f3\u58a8\u7094\u662f\u4e2a\u4ec0\u4e48\u9b3c?\u66f4\u6709\u90e8\u5206\u8111\u6d1e\u5927\u5f00\u7684\u4eba\u5df2\u7ecf\u5728\u671f\u5f85\u77f3\u58a8\u70f7\u4e86!\u6b63\u5982\u4e00\u7ebf\u660e\u661f\u6709\u5f88\u591a\u6a21\u4eff\u8005\uff0c\u501f\u540d\u4eba\u6548\u5e94\u6df7\u8ff9\u6c5f\u6e56\uff0c\u4eba\u4eec\u4e00\u5f00\u59cb\u4fbf\u8ba4\u4e3a\u77f3\u58a8\u7094\u5c31\u662f\u51ed\u501f\u77f3\u58a8\u70ef\u7684\u5149\u73af\u6210\u540d\u7684\uff0c\u76db\u540d\u4e4b\u4e0b\uff0c\u5176\u5b9e\u96be\u526f\u3002<\/p>\n
\u7136\u800c\u771f\u7684\u662f\u8fd9\u6837\u5417?<\/p>\n
\u5f53\u4eba\u4eec\u62b1\u7740\u8bd5\u8bd5\u770b\u7684\u5fc3\u6001\u53bb\u4e86\u89e3\u77f3\u58a8\u7094\u7684\u65f6\u5019\uff0c\u624d\u731b\u7136\u60ca\u89c9\uff0c\u8fd9\u771f\u662f\u4e2a\u5b9d\u8d1d\uff0c\u5b9e\u5728\u76f8\u89c1\u6068\u665a!<\/p>\n
2010\u5e74\uff0c\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u6709\u673a\u56fa\u4f53\u9662\u91cd\u70b9\u5b9e\u9a8c\u5ba4\u7814\u7a76\u4eba\u5458\u5229\u7528\u516d\u7094\u57fa\u82ef\u5728\u94dc\u7247\u7684\u50ac\u5316\u4f5c\u7528\u4e0b\u53d1\u751f\u5076\u8054\u53cd\u5e94\uff0c\u6210\u529f\u5730\u5728\u94dc\u7247\u8868\u9762\u4e0a\u901a\u8fc7\u5316\u5b66\u65b9\u6cd5\u5408\u6210\u4e86\u5927\u9762\u79ef\u78b3\u7684\u65b0\u540c\u7d20\u5f02\u5f62\u4f53\u2014\u2014\u77f3\u58a8\u7094\uff0c\u8fd9\u662f\u5728\u4e16\u754c\u4e0a\u9996\u6b21\u5927\u9762\u79ef\u5236\u5907\u51fa\u4e86\u77f3\u58a8\u7094\u8584\u819c\u3002\u5b83\u5177\u6709\u4e30\u5bcc\u7684\u78b3\u5316\u5b66\u952e\u3001\u5927\u7684\u5171\u8f6d\u4f53\u7cfb\u3001\u5bbd\u9762\u95f4\u8ddd\u3001\u4f18\u826f\u7684\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u88ab\u8a89\u4e3a\u662f\u6700\u7a33\u5b9a\u7684\u4e00\u79cd\u4eba\u5de5\u5408\u6210\u7684\u4e8c\u7094\u78b3\u7684\u540c\u7d20\u5f02\u5f62\u4f53\u3002\u7531\u4e8e\u5176\u7279\u6b8a\u7684\u7535\u5b50\u7ed3\u6784\u53ca\u7c7b\u4f3c\u7845\u4f18\u5f02\u7684\u534a\u5bfc\u4f53\u6027\u80fd\uff0c\u77f3\u58a8\u7094\u53ef\u4ee5\u5e7f\u6cdb\u5e94\u7528\u4e8e\u7535\u5b50\u3001\u534a\u5bfc\u4f53\u4ee5\u53ca\u65b0\u80fd\u6e90\u9886\u57df\u3002<\/p>\n
\u4e00\u76f4\u4ee5\u6765\uff0c\u4eba\u4eec\u603b\u6e34\u671b\u80fd\u591f\u83b7\u5f97\u5177\u6709sp\u6742\u5316\u6001\u7684\u78b3\u7684\u65b0\u540c\u7d20\u5f02\u5f62\u4f53\uff0c\u4ece\u800c\u83b7\u5f97\u4f18\u5f02\u7684\u6027\u80fd\u3002\u8fd9\u4e48\u597d\u7684\u4e8b\u60c5\uff0c\u4e3a\u4ec0\u4e48\u5916\u56fd\u4eba\u505a\u4e0d\u51fa\u6765\uff0c\u800c\u6211\u56fd\u79d1\u5b66\u5bb6\u505a\u51fa\u6765\u4e86?<\/p>\n<\/p>\n
\u77f3\u58a8\u7094\u7684\u5206\u5b50\u7ed3\u6784<\/p>\n
\u7f8e\u4e3d\u7684\u201c\u610f\u5916\u201d<\/p>\n
1968 \u5e74\u8457\u540d\u7406\u8bba\u5bb6Baughman\u901a\u8fc7\u8ba1\u7b97\u8ba4\u4e3a\u77f3\u58a8\u7094\u7ed3\u6784\u53ef\u4ee5\u7a33\u5b9a\u5b58\u5728\uff0c\u56fd\u9645\u4e0a\u7684\u8457\u540d\u529f\u80fd\u5206\u5b50\u548c\u9ad8\u5206\u5b50\u7814\u7a76\u7ec4\u90fd\u5f00\u59cb\u4e86\u76f8\u5173\u7684\u7814\u7a76\uff0c\u4f46\u662f\u5e76\u6ca1\u6709\u83b7\u5f97\u6210\u529f\u3002<\/p>\n
\u6e10\u6e10\u5730\uff0c\u4eba\u4eec\u5f00\u59cb\u6000\u7591\u77f3\u58a8\u7094\u662f\u5426\u80fd\u88ab\u4eba\u5de5\u5408\u6210\u3002<\/p>\n
\u76f4\u52302010\u5e74\uff0c\u4e2d\u79d1\u9662\u5316\u5b66\u6240\u674e\u7389\u826f\u7814\u7a76\u5458\u7b49\u63d0\u51fa\u4e86\u5728\u94dc\u7247\u8868\u9762\u4e0a\u901a\u8fc7\u5316\u5b66\u65b9\u6cd5\u539f\u4f4d\u5408\u6210\u77f3\u58a8\u7094\u5e76\u9996\u6b21\u6210\u529f\u5730\u83b7\u5f97\u4e86\u5927\u9762\u79ef(3. 61cm2)\u78b3\u7684\u65b0\u7684\u540c\u7d20\u5f02\u5f62\u4f53-\u77f3\u58a8\u7094(graphdiyne) \u8584\u819c\u3002\u5728\u8fd9\u4e00\u8fc7\u7a0b\u4e2d\u94dc\u7b94\u4e0d\u4ec5\u4f5c\u4e3a\u4ea4\u53c9\u5076\u8054\u53cd\u5e94\u7684\u50ac\u5316\u5242\u3001\u751f\u957f\u57fa\u5e95\uff0c\u800c\u4e14\u4e3a\u77f3\u58a8\u7094\u8584\u819c\u7684\u751f\u957f\u6240\u9700\u7684\u5b9a\u5411\u805a\u5408\u63d0\u4f9b\u4e86\u5927\u7684\u5e73\u9762\u57fa\u5e95\u3002<\/p>\n
\u901a\u8fc7\u8bbf\u95ee\u674e\u7389\u826f\u7814\u7a76\u5458\uff0c\u6211\u4eec\u4e86\u89e3\u5230\uff0c\u77f3\u58a8\u7094\u8fd9\u4e00\u5de8\u5927\u7684\u201c\u610f\u5916\u201d\uff0c\u5176\u5b9e\u662f\u8be5\u8bfe\u9898\u7ec4\u591a\u5e74\u7684\u7ecf\u9a8c\u79ef\u7d2f\u3002<\/p>\n
\u674e\u7389\u826f\u8bfe\u9898\u7ec4\u4ece\u6e90\u5934\u7684\u5206\u5b50\u8bbe\u8ba1\u5f00\u59cb\u8fdb\u884c\u7814\u7a76\uff0c\u6e10\u6e10\u5730\u8bd5\u7740\u5408\u6210\u4e00\u4e9b\u5206\u5b50\u7684\u7247\u6bb5\u3002\u4f46\u662f\u4ec5\u4ec5\u662f\u91cf\u53d8\u662f\u4e0d\u591f\u7684\uff0c\u76f4\u5230\u6709\u4e00\u5929\u610f\u5916\u7075\u611f\u7684\u8ff8\u53d1\u2014\u2014\u5728\u9605\u8bfb\u6587\u732e\u7684\u8fc7\u7a0b\u4e2d\uff0c\u674e\u7389\u826f\u7814\u7a76\u5458\u7a81\u7136\u8054\u60f3\u5230\u4e86\u4e00\u79cd\u5316\u5b66\u7684\u65b9\u6cd5\u6709\u53ef\u80fd\u4f7f\u77f3\u58a8\u7094\u5927\u9762\u79ef\u6210\u819c\u3002\u4e8e\u662f\uff0c\u4ed6\u4eec\u7acb\u5373\u7740\u624b\u53bb\u505a\uff0c\u8d28\u53d8\u53d1\u751f\u4e86\uff0c\u4e16\u754c\u9707\u60ca\u4e86!<\/p>\n<\/p>\n
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